Resonant inelastic x-ray scattering of methyl chloride at the chlorine K edge.
نویسندگان
چکیده
We present a combined experimental and theoretical study of isolated CH(3)Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the spin-orbit intensities, a result interpreted as due to chemical environment and singlet-triplet exchange in the molecular core levels. From analysis of the polarization-resolved data, Cl 2p(x, y) and 2p(z) electronic populations can be determined.
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عنوان ژورنال:
- The Journal of chemical physics
دوره 136 2 شماره
صفحات -
تاریخ انتشار 2012